The determination of molecular sulphur in Matsesta mineral water and its analog Novonukutskaya mineral water

Khutorianskiĭ V.A.; Smirnov A.I.; Matveev D.A.

doi:https://doi.org/

Khutorianskiĭ V.A.

Irkutskiĭ gosudarstvennyĭ universitet

Smirnov A.I.

Irkutskiĭ gosudarstvennyĭ universitet

Matveev D.A.

Central Clinical Hospital, Ministry of Internal Affairs, Moscow, Russia

The determination of molecular sulphur in Matsesta mineral water and its analog Novonukutskaya mineral water

Authors:

Khutorianskiĭ V.A., Smirnov A.I., Matveev D.A.

More about the authors

Journal: Problems of Balneology, Physiotherapy and Exercise Therapy. 2014;91(6): 48‑51

Read: 1254 times

Download PDF (RU)

Contact the author

Table of contents

To cite this article:

Khutorianskiĭ VA, Smirnov AI, Matveev DA. The determination of molecular sulphur in Matsesta mineral water and its analog Novonukutskaya mineral water. Problems of Balneology, Physiotherapy and Exercise Therapy. 2014;91(6):48‑51. (In Russ.)

Подписка 2026 Вопросы курортологии, физиотерапии и лечебной физической культуры (Problems of Balneology, Physiotherapy and Exercise Therapy)

Использование инфографики авторами научных работ

Close metadata

Recommended articles:

Development of conditions for determination of imidazole derivatives in the blood using chromatography-mass spectrometry. Forensic Medical Expertise. 2025;(3):32-37

Abstract:

The method of microcolumn reversed phase high performance liquid chromatography (rp-HPLC) was employed to determine the content of elemental sulphur in mineral waters. The study envisaged the analysis of the samples of sulphide-containing mineral waters Novonukutskaya and Matsesta obtained by the solid phase extraction technique. Based on these data, the authors discuss the origin and the circulation of sulphur in the hydrogen sulphide sources. The elution conditions selected in this study ensured the high-resolution separation of the octasulphur peak from the peaks of allotropic components of the extract whereas the two-wave detection technique allowed to identify the peaks of molecular sulphur.

Keywords:

liquid chromatography

solid-phase extraction

sulphur

polysulphides

sulphans

"Matsesta"

Authors:

Khutorianskiĭ V.A.

Irkutskiĭ gosudarstvennyĭ universitet

Smirnov A.I.

Irkutskiĭ gosudarstvennyĭ universitet

Matveev D.A.

Central Clinical Hospital, Ministry of Internal Affairs, Moscow, Russia

Close metadata

References:

Shpeizer G.M., Khutoryansky V.A., Rodionova V.A., Mineeva L.A., Smirnov A.I., Glebets V.I., Malyshkina N.A., Yushkov G.G., Igumenshcheva V.V., Shchukina O.G., Benemansky V.V., Buts M.M. Sovremennye tekhnologii vydeleniya bal'neologicheskikh preparatov iz mineral'nykh vod [The modern technologies for the isolation of balneotherapeutic preparations from mineral waters]. Voprosy kurortologii, fizioterapii I lechebnoy fizicheskoy kul'tury. 2010; 4: 41-2. [In Russ.].
Hallberg K.B., Dopson M., Lindstrom E.B. Reduced sulfur compound oxidation by Thiobacillus caldus. J. Bacteriol. 1996; 178 (1): 6-11.
Shpeizer G.M., Khutoryansky V.A., Rodionova V.A., Mineeva L.A., Smirnov A.I., Glebets V.I., Malyshkina N.A., Yushkov G.G., Igumenshcheva V.V., Shchukina O.G., Benemansky V.V., Buts M.M. Sposob polucheniya sredstva, obladayushchego ranozazhivlyayushchey aktivnost'yu. Patent No 2357740. Rossiyskaya Federatsiya. Opublikovano 10.06.2009 [The method for the production of the preparation possessed of the wound-healing activity. Patent No 2357740. Russian Federation. Publication date: 10.06.2009]. [In Russ.].
Khoroshko L.O., Belyakova Yu.G., Viktorovsky I.V., Paasivirta Ya. Organicheskie polisul'fidy v donnykh otlozheniyakh Finskogo zaliva [Organic polysulfides contained in the bottom deposits of the Gulf of Finland]. Khimiya v interesakh ustoichivogo razvitiya. 2007; 15 (1): 109-16. [In Russ.].
Shpeizer G.M., Smirnov A.I., Khutoryansky V.A., Mineeva L.A., Rodionova V.A. Novye dannye o sostave organicheskikh veshchestv v mineral'nykh vodakh [The new data about the composition of the organic substances in mineral waters]. Sovremennye problemy nauki I obrazovaniya. 2006; 2: 62-4. [In Russ.].
Bekhterev V.N., Georgiadi-Avdienko K.A., Khodasevich L.S., Pronina T.V. Predvaritel'nye issledovaniya biologicheskoy aktivnosti parofaznykh ekstraktov organicheskikh veshchestv matsestinskikh mineral'nykh vod [The preliminary investigations into the biological activity of the vapour-phase extracts of organic substances isolated from Matsesta mineral waters]. Voprosy kurortologii, fizioterapii I lechebnoy fizicheskoy kul'tury. 2008; 1: 32-4. [In Russ.].
Dash K., Thangavel S., Krishnamurthy N.V., Rao S.V., Karunasagara D., Arunachalam J. Ultrasound-assisted analyte extraction for the determination of sulfate and elemental sulfur in zinc sulfide by different liquid chromatography techniques. Analyst. 2005; 130: 498-501.
Azarova I.N., Gorshkov A.G., Grachev M.A., Korzhova E.N., Smagunova A.N. Opredelenie elementarnoy sery v donnykh osadkakh metodom vysokoeffektivnoy zhidkostnoy khromatografii [The determination of elemental sulphur in the bottom deposits with the use of high performance liquid chromatography]. Zhurnal analiticheskoy khimii. 2001; 56 (10): 1062-6. [In Russ.].
Khutoryansky V.A., Smirnov A.I., Namsaraev B.B., Khakhinov V.V., Gambuzhapova L.B. Analiz molekulyarnoy sery sul'fidnykh mineral'nykh vod. V kn.: "Pit'evaya voda v XXI veke": nauchno-praktichesksys konferentsiya s mezhdunarodnm uchastiem. Irkutsk, 23 - 28 sentyabrya 2013 g. [The analysis of molecular sulphur in sulfide-comtaining mineral waters. In: "Drinking water in the XXI century": the scientific and practical conference with the international participation. Irkutsk, 23 - 28 Septemner 2013]. Irkutsk; 2013: 95. [In Russ.].
Steudel R. The chemistry of organic polysulfanes R-S-(n)-R (n>2). Chem. Rev. 2002; 102 (11): 3905-45.
Akhmedova Yu.I., Shinkar' E.V., Berberova N.T. Issledovanie deistviya okisliteley na protsess razlozheniya polisul'fanov v gazovoy srede [The investigation of the action of the oxidants on the process of polysulfane decomposition in the gaseous milieu]. Vestnik Astrakhanskogo gosudarstvennogo tekhnicheskogo universiteta. 2007; 6: 8-13. [In Russ.].
Mathai J.C., Missner A., Kügler P., Saparov S.M., Zeidel M.L., Lee J.K., Pohl P. No facilitator required for membrane transport of hydrogen sulfide. Proc. Natl. Acad. Sci. USA. 2009; 106 (39): 16633-8.